When I was in grade 5, you could write to NASA, and they would send you whatever information or pictures you asked for and a lot more. On one occasion, I got a large envelope in our mailbox with a beautiful poster of the Apollo 11 mission. I brought it to school to share it with my classmates. My teacher was impressed. She put it on the classroom wall, but at the end of the year, she liked it so much that she refused to give it back to me!
Yesterday I came across the following from an old NASA poster, that may or may not have been from the one I once owned:

The first thing that caught my attention was the ratio of liquid hydrogen to that of liquid oxygen in Stage 2 of the rocket, which as the poster explains, takes the rocket from an altitude of 36 miles to 108 miles where it attains its orbital velocity. I guess not to scare 10 year-olds, they express the figures in gallons and not in moles, which would have been more meaningful. Moles are bundles of molecules and proportional to them so that from a chemical equation you know, for example, that it takes two moles of hydrogen to react with every one mole of oxygen.
Why? Since atoms are not destroyed in chemical reactions it takes to two molecules of diatomic hydrogen to bond to one molecule of diatomic oxygen to produce two molecules of water. That way, 4 atoms of hydrogen and a pair of oxygens go into the reaction, and the same number of atoms of hydrogen and oxygen are part of the water being produced.
But did NASA pack the second stage with such a ratio of 2:1? It turns out, no. At first I thought it was because an exact stoichiometric ratio of 2 parts hydrogen to 1 part oxygen is too explosive (stoichiometric just means the ratio from the balanced chemical equation). If for example, you fill a balloon with hydrogen and just rely on the oxygen from the air to react with it after you ignite it, the explosion is a lot more tame than if you ignite two parts of hydrogen and 1 part of oxygen in a balloon. You’ll even remark no color in the latter case. But when there is a shortage of oxygen gas, the excess hydrogen glows orange by the same mechanism that the unburnt particles incandesce in a candle flame. Film footage of the fuel burning from the second stage of the Saturn V rocket confirms that there is excess hydrogen. So why include more? A small symmetric molecule like hydrogen stores less vibrational and rotational energy for a given amount of heat from combustion. By having excess (unburnt) hydrogen, more of the translational energy it picks up from the combustion can be converted to kinetic energy. That results in a higher exhaust velocity, implying that the rocket gets more of a push forward.
So how do you go about calculating the mole-ratio from the chart’s 267 700 US gallons of liquid hydrogen and 87 400 gallons of liquid oxygen? We should note that the problem would be trivial if the gallons were just volumes of gases. You see thanks to Avogadro, we’ve known for more than two centuries that equal volumes of different gases under the same conditions of temperature and pressure have the same number of molecules. That’s because in the gas state, the volume is not determined by the size of individual molecules. They are so small compared to the distance between them that each atom’s size is irrelevant. But in the liquid or solid state, an atom’s radius does matter. So after converting US gallons to liters, you need to convert the volume of each liquid into mass by multiplying by its density (1.14 kg/L for liquid oxygen and 0.071 kg/L for liquid hydrogen) and then converting to moles by dividing each by its molar mass ( 0.0320 kg/mole for oxygen and 0.0020 kg/mole for hydrogen). When that’s done we obtain a mole-ratio of 3.05 parts of hydrogen for every 1 part of oxygen instead of the stoichiometric ratio of 2 : 1. The fuel mixture in the rocket’s second stage was fuel-rich indeed.
But what you really want to know is: does my grade 5 teacher still have my poster? Like many people of their age, they have no online presence and are impossible to reach. 🙂